Diisonicotinium penta­chloridoanti­monate(III) monohydrate

N-Methyl­piperazinediium penta­chloridoanti­monate(III) monohydrate

The asymmetric unit of the title compound, (C(5)H(14)N(2))[SbCl(5)]·H(2)O, consists of an N-methyl-piperazinediium cation, a penta-chloridoanti-monate anion with the Sb(III) ion in a slightly distorted square-pyramidal coordination environment, and one solvent water mol-ecule. The crystal structure is stabilized by inter-molecular N-H⋯Cl, O-H⋯Cl and N-H⋯O hydrogen bonds.

2-(3-Pyridinio)benzimidazolium penta­chloridoanti­monate(III) monohydrate

In the title compound, (C(12)H(11)N(3))[SbCl(5)]·H(2)O, the Sb(III) centre is surrounded by five Cl atoms and displays a distorted square-pyramidal coordination geometry. The dihedral angle formed by the plane of the imidazole ring system with the pyridine ring is 4.380 (15)°. The crystal structure is stabilized by N-H⋯Cl, O-H⋯Cl and N-H⋯O hydrogen bonds, forming a three-dimensional network.

Dimorpholinium penta­chloridoanti­monate(III)

The asymmetric unit of the title compound, (C(4)H(10)NO)(2)[SbCl(5)], consists of two morpholinium cations in chair conformations, and a penta-chloridoanti-monate dianion with the Sb(III) ion in a slightly distorted square-pyramidal coordination environment. The morpholinium cations are connected to each other by N-H⋯O hydrogen bonds, and they link the chloride anions and the anti-monate SbCl(3...

Polymeric aqua(glutarato)(hydrogen glutarato)lanthanum(III) monohydrate

Poly[[diaqua­hemi-μ4-oxalato-μ2-oxalato-praseodymium(III)] monohydrate]

In the title complex, {[Pr(C(2)O(4))(1.5)(H(2)O)(2)]·H(2)O}(n), the Pr(III) ion, which lies on a crystallographic inversion centre, is coordinated by seven O atoms from four oxalate ligands and two O atoms from two water ligands; further Pr-O coordination from tetra-dentate oxalate ligands forms a three-dimensional structure. The compound crystallized as a monohydrate, the water mol-ecule occup...